Hierarchical aggregation in a complex fluid; The Role of isomeric interconversion

Massey, D.*; Williams, C. D.*; Mu, J.*; Masters, A. J.*; Motokawa, Ryuhei; Aoyagi, Noboru; Ueda, Yuki; Antonio, M. R.*

Journal of Physical Chemistry B, 127(9), p.2052 - 2065, 2023/03

https://doi.org/10.1021/acs.jpcb.2c07527

The pH-dependence of the extrated species of Eu and Am by N,N'-demethyl-N,N'-dehexyl-3-oxapentanediamide and thenoyltrifluoroacetone

Sasaki, Yuji

Bunseki Kagaku, 46(3), p.181 - 186, 1997/00

https://doi.org/10.2116/bunsekikagaku.46.181

no abstracts in English

Literature survey on extractants for liquid-liquid extraction applied to nuclear fuel cycles

;

PNC TN8420 95-002, 140 Pages, 1995/01

PNC-TN8420-95-002.pdf:3.16MB

In the field of uranium ore refining and spent fuel reprocessing, a lot of extractants capable of recovering actinides have been innovated, and some of which have been developed in actual industrial scale processes. Extractability against trivalent actinides on each extractants were evaluated in this report. And as for the compounds which showed excellent extractability for Americium, their extraction characteristics for trivalent actinides, such as extraction behavior, mechanism, ligand structure and conformation of complexes, were evaluated, and filed as data-base. Based on these works, some of extractant were newly identified as candidate to apply Americium recovering. The most appropriate compounds for trivalent actinide separation can be generally found in the neutral bidentate organic compound groups: Especially, some derivatives belongs to Diphosphineoxide, Carbamoyl-methylphosphine oxide and Propandiamide were superior to give sufficiently excellent property even in higher nitric acid(13M) solutions. Innovative research towards developping new extractants and extraction system seems to be directed to ; (1)investigate new types of extractant sustained by a different kind of complexing mechanism, (2)evaluate synergistic effect of adducts, diluents even including conventional extractants.

SANS and EXAFS study of hierarchical structure assembled by coordination species in biphasic solvent extraction

Motokawa, Ryuhei; Kobayashi, Toru; Endo, Hitoshi*; Suzuki, Shinichi; Yaita, Tsuyoshi; Shiwaku, Hideaki

no journal, , 

Third phase formation induced by a growth of hierarchical aggregation structure in biphasic solvent extraction systems

Motokawa, Ryuhei

no journal, , 

Nanoscopic solute architectures formed in the organic phase during liquid-liquid extraction

Motokawa, Ryuhei

no journal, , 

no abstracts in English